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Swift
2015-Jun-23, 01:46 PM
R&D Magazine (http://www.rdmag.com/news/2015/06/salt-key-unlocking-interiors-neptune-uranus?et_cid=4638789&et_rid=54636800&type=cta)


The interiors of several of our solar system’s planets and moons are icy, and ice has been found on distant extrasolar planets, as well. But these bodies aren’t filled with the regular kind of water ice that you avoid on the sidewalk in winter. The ice that’s found inside these objects must exist under extreme pressures and high-temperatures, and potentially contains salty impurities, too.

New research from a team including Carnegie’s Alexander Goncharov focuses on the physics underlying the formation of the types of ice that are stable under the paradoxical-seeming conditions likely to be found in planetary interiors. Their work, published by Proceedings of the National Academy of Sciences, could challenge current ideas about the physical properties found inside icy planetary bodies.


Under high pressures, the variety of possible ice structures shrinks, just as the space between its hydrogen-bonded oxygen atoms does as the ice grows denser. When pressure is increased to more than about 20,000 times Earth’s atmosphere (2 gigapascals), this number of possible ice structures is reduced to just two—ice VII and ice VIII. Ordinary ice has a hexagonal structure. Ice VII has a cubic structure. Ice VIII has a tetragonal structure.

As the pressure increases further, both forms of ice transform to another phase called ice X. This happens at pressures around 600,000 times Earth’s atmosphere (60 gigapascals), which would be comparable to the pressure conditions found in the interior of an icy-cored planet, like Neptune or Uranus. Ice X has a whole new kind of symmetrical lattice structure. It’s called non-molecular ice, because the water molecule is broken apart and the hydrogen atoms are shared between neighboring oxygens.

Under similar pressures but higher temperatures, it has been suggested that ice X could possibly transform into a phase of ice that can conduct electricity as hydrogen atoms move freely around the oxygen lattice. But how such ice would be formed at the temperatures found in planetary interiors has remained mysterious.

Because the interiors of icy planetary bodies might also be salty, due to interactions between the ice and the surrounding rocks or a liquid ocean, lead author Livia Eleonora Bove of the CNRS & Université Pierre et Marie Curie in France and the Ecole Polytechnique Federal de Lausanne in Switzerland and the rest of the team studied the effects of salts on the formation of the ice X from ice VII.


The presence of salt could also possible create the conditions under which the theorized electrically conducting type of ice would form. If so, this could explain the magnetic fields of Uranus and Neptune, the team proposed.

antoniseb
2015-Jun-23, 03:06 PM
Just so long as we don't bring back any Ice IX (assuming KV was correct) I think this is fascinating stuff.